Combinations of Errors

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Study Text: "Essential Mathematics and Statistics for Science", 2nd ed, G Currell and A A Dowman (Wiley-Blackwell)

QVA (questions and video answers) Tutorials:

Combining uncertainties / propagation of errors Study Text: Section 8.3.3 (p226)
Errors and uncertainties in concentrations and dilutions  (video feedback in preparation) Study Text: Section 8.3.3 (p226)

Combining and propagating random errors/uncertainties

Assuming random uncertainties where:
 ua and ub are the absolute uncertainties in variables, a and b.
 Rua and Rub are the relative percentage uncertainties in variables, a and b.

To convert between absolute and relative percentage uncertainties:
     Rua = 100 × ua / a    and    ua = a × Rua / 100      etc

To calculate combined uncertainties use absolute or relative uncertainties depending on the combination of variables which give a final value x:
 • x = a + b or x = a - b :- then use ux = √{(ua)2 + (ub)2}

 • x = a×b or x = a/b :- then use Rux = √{(Rua)2 + (Rub)2}

 • x = k×a (where k is a constant) :- then use Rux = Rua or ux = k×ua

 • x = an (where n is a constant) :- then use Rux = n×(Rua)

Note that it is possible to use the simple (not percentage) relative uncertainties (i.e. without introducing the ‘100’ into the calculations), but it is necessary to be consistent throughout the calculation. We use percentage uncertainty here because many scientists are more familiar with expressing relative uncertainty as a percentage.

See Study Text: Section 8.3.3

Absolute and relative uncertainty

The uncertainty of ±0.03 cm3 in a 10 cm3 class A graduated pipette would be considered as the absolute uncertainty.

The relative uncertainty in the same situation is given by:
     Relative uncertainty = Absolute uncertainty / Value
e.g. relative uncertainty in the above example = 0.03 cm3 / 10 cm3 = 0.003

Percentage uncertainty is the relative uncertainty expressed as a percentage
e.g. percentage uncertainty in the above example = 100 × 0.03 cm3 / 10 cm3 = 0.3%

Absolute uncertainties have the same units as the value itself (e.g. cm3 in the above example), relative uncertainties are a simple ratio with no units, and percentage uncertainties are ratios expressed as percentages.